Significance of the Connecting Position between Zn(II) Porphyrin and Re(I) Bipyridine Tricarbonyl Complex Units in Dyads for Room-Temperature Phosphorescence and Photocatalytic CO<sub>2</sub> Reduction: Unexpected Enhancement by Triethanolamine in Catalytic Activity

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چکیده

We synthesized three new dyads composed of a Zn porphyrin and fac -Re(bpy)(CO) 3 Br (bpy = 2,2'-bipyridine) units, ZnP- n Bpy=Re ( 4, 5, 6), in which the is directly connected...

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2023

ISSN: ['2041-6520', '2041-6539']

DOI: https://doi.org/10.1039/d3sc02430j